NIOSH Pocket Guide

Acrylonitrile

CAS

107-13-1

CH2=CHCN

RTECS

AT5250000

Synonyms & Trade Names


Acrylonitrile monomer, AN, Cyanoethylene, Propenenitrile, 2-Propenenitrile, VCN, Vinyl cyanide

DOT ID & Guide
 

1093 131P (inhibited)

Exposure
Limits

NIOSH REL: Ca TWA 1 ppm C 10 ppm [15-minute] [skin]
OSHA PEL: [1910.1045] TWA 2 ppm C 10 ppm [15-minute] [skin]
IDLH

Ca [85 ppm] 

Conversion

1 ppm = 2.17 mg/m3

Physical Description
 

Colorless to pale-yellow liquid with an unpleasant odor. [Note: Odor can only be detected above the PEL.]

MW: 53.1
 
BP: 171°F
 
FRZ: -116°F
 
Sol: 7%
 
VP: 83 mmHg
 
IP: 10.91 eV
 

 
Sp.Gr: 0.81
 
Fl.P: 30°F
 
UEL: 17%
 
LEL: 3.0%
 

 
Class IB Flammable Liquid: Fl.P. below 73°F and BP at or above 100°F.
Incompatibilities & Reactivities


Strong oxidizers, acids & alkalis; bromine; amines [Note: Unless inhibited (usually with methylhydroquinone), may polymerize spontaneously or when heated or in presence of strong alkali. Attacks copper.]

Personal Protection & Sanitation


Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet (flammable)
Change: No recommendation
Provide: Eyewash, Quick drench
 

First Aid


Eye: Irrigate immediately
Skin: Water wash immediately
Breathing: Respiratory support
Swallow: Medical attention immediately
 

Respirator Recommendations

NIOSH
At concentrations above the NIOSH REL, or where there is no REL, at any detectable concentration:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister/Any appropriate escape-type, self-contained breathing apparatus
 

Exposure Routes

inhalation, skin absorption, ingestion, skin and/or eye contact

Symptoms

Irritation eyes, skin; asphyxia; headache; sneezing; nausea, vomiting; lassitude (weakness, exhaustion), dizziness; skin vesiculation; scaling dermatitis; [potential occupational carcinogen]

Target Organs

Eyes, skin, cardiovascular system, liver, kidneys, central nervous system

 

Cancer Site

[brain tumors, lung & bowel cancer]

Fuente: U.S. Department of Health and Human Services

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